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71.
The role of the oxygen fugacity on the incorporation of nitrogen in basaltic magmas has been investigated using one atmosphere high temperature equilibration of tholeiitic-like compositions under controlled nitrogen and oxygen partial pressures in the [C-N-O] system. Nitrogen was extracted with a CO2 laser under high vacuum and analyzed by static mass spectrometry. Over a redox range of 18 oxygen fugacity log units, this study shows that the incorporation of nitrogen in silicate melts follows two different behaviors. For log fO2 values between −0.7 and −10.7 (the latter corresponding to IW − 1.3), nitrogen dissolves as a N2 molecule into cavities of the silicate network (physical solubility). Nitrogen presents a constant solubility (Henry’s) coefficient of 2.21 ± 0.53 × 10−9 mol g−1 atm−1 at 1425°C, identical within uncertainties to the solubility of argon. Further decrease in the oxygen fugacity (log fO2 between −10.7 and −18 corresponding to the range from IW − 1.3 to IW − 8.3) results in a drastic increase of the solubility of nitrogen by up to 5 orders of magnitude as nitrogen becomes chemically bounded with atoms of the silicate melt network (chemical solubility). The present results strongly suggest that under reducing conditions nitrogen dissolves in silicate melts as N3− species rather than as CN cyanide radicals. The nitrogen content of a tholeiitic magma equilibrated with N2 is computed from thermochemical processing of our data set as
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72.
Quaternary sedimentary deposits along the structural depression of the San Andreas fault (SAF) zone north of San Francisco in Marin County provide an excellent record of rates and styles of neotectonic deformation in a location near where the greatest amount of horizontal offset was measured after the great 1906 San Francisco earthquake. A high-resolution gravity survey in the Olema Valley was used to determine the depth to bedrock and the thickness of sediment fill along and across the SAF valley. In the gravity profile across the SAF zone, Quaternary deposits are offset across the 1906 fault trace and truncated by the Western and Eastern Boundary faults, whose youthful activity was previously unknown. The gravity profile parallel to the fault valley shows a basement surface that slopes northward toward an area of present-day subsidence near the head of Tomales Bay. Surface and subsurface investigations of the late Pleistocene Olema Creek Formation (Qoc) indicate that this area of subsidence was located further south during deposition of the Qoc and that it has migrated northward since then. Localized subsidence has been replaced by localized contraction that has produced folding and uplift of the Qoc. This apparent alternation between transtension and transpression may be the result of a northward-diverging fault geometry of fault strands that includes the valley-bounding faults as well as the 1906 SAF trace. The Vedanta marsh is a smaller example of localized subsidence in the fault zone, between the 1906 SAF trace and the Western Boundary fault. Analyses of Holocene marsh sediments in cores and a paleoseismic trench indicate thickening, and probably tilting, toward the 1906 trace, consistent with coseismic deformation observed at the site following the 1906 earthquake.New age data and offset sedimentary and geomorphic features were used to calculate four late Quaternary slip rate estimates for the SAF at this latitude. Luminescence dates of 112–186 ka for the middle part of the Olema Creek Formation (Qoc), the oldest Quaternary deposit in this part of the valley, suggest a late Pleistocene slip rate of 17–35 mm/year, which replaces the unit to a position adjacent to its sediment source area. A younger alluvial fan deposit (Qqf; basal age 30 ka) is exposed in a quarry along the medial ridge of the fault valley. This fan deposit has been truncated on its western side by dextral SAF movement, and west-side-down vertical movement that has created the Vedanta marsh. Paleocurrent measurements, clast compositions, sediment facies distributions, and soil characteristics show that the Bear Valley Creek drainage, now located northwest of the site, supplied sediment to the fan, which is now being eroded. Restoration of the drainage to its previous location provides an estimated slip rate of 25 mm/year. Furthermore, the Bear Valley Creek drainage probably created a water gap located north of the Qqf deposit during the last glacial maximum 18 ka. The amount of offset between the drainage and the water gap yields an average slip rate of 21–30 mm/year. Finally, displacement of a 1000-year-old debris lobe approximately 20 m from its hillside hollow along the medial ridge indicates a minimum late Holocene slip rate of 21–25 mm/year. Similarity of the late Pleistocene rates to the Holocene slip rate, and to previous rates obtained in paleoseismic trenches in the area, indicates that the rates may not have changed over the past 30 ka, and perhaps the past 200–400 ka. Stratigraphic and structural observations also indicate that valley-bounding faults were active in the late Pleistocene and suggest the need for further study to evaluate their continued seismic potential.  相似文献   
73.
Research was carried out to assess the potential of imaging radar systems formonitoring forest fire danger. In Canada, daily forest fire danger ratings are generated by the Canadian ForestFire Danger Rating System (CFFDRS), based on estimates of fire weather indices (FWI) and measured foliar moisturecontent (FMC). To evaluate the potential of imaging radar, an experiment was conducted using test sitesconsisting of jack pine, black spruce and white spruce stands located in the MacKenzie river basin, NorthwestTerritories, Canada. Radar image intensity values from ERS-1 SAR imagery collected over these stands in 1994 werecompared to FWI indices and FMC data. FWI indices were calculated using data from local weather stations.Seasonal trends in radar backscatter (0) were shown to correlate with temperature and precipitation. Significant relationships were found between 0 and FWI codes and indices, particularly in thecase of the black spruce stands, with slow-drying fuels, like duff moisture code (DMC), drought code (DC), and build-upindex (BUI). Rates of changes in 0were related to rates of changes in FMC, particularly in the case ofthe jack pine stands for old FMC and in the case of white spruce stands for composite FMC.  相似文献   
74.
The influence of water on melting of mantle peridotite   总被引:47,自引:8,他引:39  
This experimental study examines the effects of variable concentrations of dissolved H2O on the compositions of silicate melts and their coexisting mineral assemblage of olivine + orthopyroxene ± clinopyroxene ± spinel ± garnet. Experiments were performed at pressures of 1.2 to 2.0 GPa and temperatures of 1100 to 1345 °C, with up to ∼12 wt% H2O dissolved in the liquid. The effects of increasing the concentration of dissolved H2O on the major element compositions of melts in equilibrium with a spinel lherzolite mineral assemblage are to decrease the concentrations of SiO2, FeO, MgO, and CaO. The concentration of Al2O3 is unaffected. The lower SiO2 contents of the hydrous melts result from an increase in the activity coefficient for SiO2 with increasing dissolved H2O. The lower concentrations of FeO and MgO result from the lower temperatures at which H2O-bearing melts coexist with mantle minerals as compared to anhydrous melts. These compositional changes produce an elevated SiO2/(MgO + FeO) ratio in hydrous peridotite partial melts, making them relatively SiO2 rich when compared to anhydrous melts on a volatile-free basis. Hydrous peridotite melting reactions are affected primarily by the lowered mantle solidus. Temperature-induced compositional variations in coexisting pyroxenes lower the proportion of clinopyroxene entering the melt relative to orthopyroxene. Isobaric batch melting calculations indicate that fluid-undersaturated peridotite melting is characterized by significantly lower melt productivity than anhydrous peridotite melting, and that the peridotite melting process in subduction zones is strongly influenced by the composition of the H2O-rich component introduced into the mantle wedge from the subducted slab. Received: 7 April 1997 / Accepted: 9 January 1998  相似文献   
75.
In the beginning of the 20th century, many streams in western Iowa were channelized to reduce flooding and to open swamp land to cultivation. Channel straightening accomplished its goal. However, it resulted in greater streamflow velocities, causing stream channels to degrade. This degradation has resulted in significant loss of land and damage to transportation and communications infrastructure in western Iowa and in several states in the United States. Baumel et al. (1994; Impact of Degrading Western Iowa Streams on Private and Public Infrastructure Costs. Final Report Iowa DOT HR-352, Stream Stabilization in Western Iowa) estimated the historical cost of this degradation on land loss and damage to transportation and communications infrastructure in western Iowa. The purpose of this paper is to extend the Baumel et al. analysis to estimate future degradation costs on 141 streams in western Iowa. It also presents two types of degradation cost estimates. One is a time neutral cost that does not consider the dates on which the degradation costs are incurred. The second is a time value cost which considers the dates on which the costs are incurred and then discounts these costs back to 1992 dollars. The time value costs are the more accurate estimates of the cost of future degradation in 1992 dollars and should be used to evaluate stream stabilization project proposals.  相似文献   
76.
At Medicine Lake Volcano, California, the compositional gap between andesite (57–62 wt.% SiO2) and rhyolite (73–74 wt.% SiO2) has been generated by fractional crystallization. Assimilation of silicic crust has also occurred along with fractionation. Two varieties of inclusions found in Holocene rhyolite flows, hornblende gabbros and aphyric andesites, provide information on the crystallization path followed by lavas parental to the rhyolite. The hornblende gabbros are magmatic cumulate residues and their mineral assemblages are preserved evidence of the phases that crystallized from an andesitic precursor lava to generate the rhyolite lavas. The andesitic inclusions represent samples of a parental andesite and record the early part of the differentiation history. Olivine, plagioclase and augite crystallization begins the differentiation history, followed by the disappearance of olivine and augite through reaction with the liquid to form orthopyroxene and amphibole. Further crystallization of the assemblage plagioclase, amphibole, orthopyroxene, magnetite, and apatite from a high-SiO2 andesite leads to rhyolite. This final crystallization process occurs on a cotectic that is nearly horizontal in temperature-composition space. Since a large amount of crystallization occurs over a limited temperature interval, a compositional gap develops between rhyolite and high SiO2 andesite.Liquidus surfaces with shallow slopes in temperature-composition space are characteristic of several late-stage crystallization assemblages in the andesite to rhyolite compositional range. Experimentally produced plagioclase+ amphibole+orthopyroxene+magnetite and plagioclase+ augite+low-Ca pyroxene+magnetite cotectics have liquidus slopes that are nearly flat. At other calc-alkaline volcanic centers crystallization processes involving large compositional changes over small temperature intervals may also be important in the development of bimodal volcanism (i.e. the existence of a composition gap). At Mt. Mazama and Mt. St. Helens, USA and Aso Caldera and Shikotsu, Japan the amphibole-bearing assemblage was important. At Krakatau, Indonesia and Katmai, USA, an augite+orthopyroxene-bearing assemblage was important. In addition to its role in the production of a compositional gap between intermediate and rhyolitic lavas, the crystallization process increases the H2O content of the residual liquid. This rapid increase in residual liquid volatile content which results from the precipitation of a large proportion of crystalline solids may be an important factor among several that lead to explosive silicic eruptions.  相似文献   
77.
78.
Nitrogen concentrations and isotopic compositions were measured by ion microprobe scanning imaging in two interplanetary dust particles L2021 K1 and L2036 E22, in which imaging of D/H and C/H ratios has previously evidenced the presence of D-rich macromolecular organic components. High nitrogen concentrations of 10-20 wt% and δ15N values up to +400‰ are observed in these D-rich macromolecular components. The previous study of D/H and C/H ratios has revealed three different D-rich macromolecular phases. The one previously ascribed to macromolecular organic matter akin the insoluble organic matter (IOM) from carbonaceous chondrites is enriched in nitrogen by one order of magnitude compared to the carbonaceous chondrite IOM, although its isotopic composition is still similar to what is known from Renazzo (δ15N = +208‰).The correlation observed in macromolecular organic material between the D- and 15N-excesses suggests that the latter originate probably from chemical reactions typical of the cold interstellar medium. These interstellar materials preserved to some extent in IDPs are therefore macromolecular organic components with various aliphaticity and aromaticity. They are heavily N-heterosubstituted as shown by their high nitrogen concentrations >10 wt%. They have high D/H ratios >10−3 and δ15N values ≥ +400‰. In L2021 K1 a mixture is observed at the micron scale between interstellar and chondritic-like organic phases. This indicates that some IDPs contain organic materials processed at various heliocentric distances in a turbulent nebula. Comparison with observation in comets suggests that these molecules may be cometary macromolecules. A correlation is observed between the D/H ratios and δ15N values of macromolecular organic matter from IDPs, meteorites, the Earth and of major nebular reservoirs. This suggests that most macromolecular organic matter in the inner solar system was probably issued from interstellar precursors and further processed in the protosolar nebula.  相似文献   
79.
We examine a database containing the results of 40Ar/39Ar step-heating experiments performed on 194 basement K-feldspars to recover thermal history information. Qualitative examination of 40Ar/39Ar systematics reveals that about half of the K-feldspars examined are sufficiently well behaved to be suitable for thermal history analysis. Correlation algorithms are developed to quantitatively assess the degree to which age and 39Ar release spectra are compatible with the same volume diffusion process. Upon applying these methods, we find that 65% of all samples yield correlation coefficients in excess of 0.8, whereas roughly 40% give values above 0.9. We further compare the observed correlation behavior with that predicted from the multidiffusion domain model and find good agreement for samples with correlation coefficients above 0.9. In contrast, hydrous phases unstable under in vacuo heating and K-feldspars with highly disturbed age spectra yield poorly correlated age and diffusion properties. The high degree of correlation exhibited by the majority of K-feldspars we have analyzed validates extrapolation of experimentally determined diffusion properties to conditions attending natural Ar loss within the crust. Despite this, a significant number of basement K-feldspars analyzed by the step-heating method yield 40Ar/39Ar systematics that are clearly problematic for thermal history analysis. We numerically explore the effects of low-temperature alteration of K-feldspar on thermochronological analysis and identify a range of conditions under which information is progressively lost. Finally, we demonstrate the insensitivity of thermal history calculations to detailed knowledge of the diffusion mechanism by introducing the heterogeneous diffusion model. We find that the multidiffusion domain approach can successfully recover imposed thermal histories from heterogeneous diffusion-type crystals and conclude that most details of the interpretive model employed are of secondary importance. The only requirement for recovering thermal histories from K-feldspar 40Ar/39Ar step-heating results is that argon loss proceeds by volume diffusion and that laboratory argon release adequately mimics the natural diffusion boundaries and mechanisms—a requirement implicitly met by those samples exhibiting high degrees of correlation.  相似文献   
80.
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